Removal of paracetamol from aqueous solution with zinc oxide nanoparticles obtained by green synthesis from purple basil (Ocimum basilicum L.) waste

Removal of paracetamol from aqueous solution with zinc oxide nanoparticles obtained by green synthesis from purple basil (Ocimum basilicum L.) waste

2024 | Alper Solmaz, Talip Turna, Ayşe Baran
This study investigates the removal of paracetamol (PCM) from pharmaceutical waste using zinc oxide nanoparticles (OB-ZnO NPs) synthesized from *Ocimum basilicum* (OB) plant waste. The synthesized OB-ZnO NPs were characterized using various techniques, including X-ray diffraction (XRD), Brunauer–Emmett–Teller (BET), scanning electron microscopy (SEM), energy dispersive X-ray (EDX), Fourier transform infrared spectroscopy (FT-IR), dynamic light scattering (DLS), Zetasizer, thermogravimetry-differential thermal analysis (TGA-DTA), and UV-vis spectroscopy. The crystal structure of the NPs was found to be hexagonal wurtzite with a particle size of 30.39 nm, a surface area of 13.826 m²/g, and a pore volume of 0.0475 cm³/g. The zeta potential of the NPs was −22.1 mV, and they showed a mass loss of 33% at about 750 °C, indicating their durability at high temperatures. Kinetic and isotherm models were used to determine the most suitable model for PCM removal, with the Elovich model showing an R² value of 0.989 and the Redlich-Peterson model showing an R² value of 0.999. The adsorption efficiency of PCM was 23 mg/g, demonstrating the potential of OB-ZnO NPs for removing pharmaceutical wastes.This study investigates the removal of paracetamol (PCM) from pharmaceutical waste using zinc oxide nanoparticles (OB-ZnO NPs) synthesized from *Ocimum basilicum* (OB) plant waste. The synthesized OB-ZnO NPs were characterized using various techniques, including X-ray diffraction (XRD), Brunauer–Emmett–Teller (BET), scanning electron microscopy (SEM), energy dispersive X-ray (EDX), Fourier transform infrared spectroscopy (FT-IR), dynamic light scattering (DLS), Zetasizer, thermogravimetry-differential thermal analysis (TGA-DTA), and UV-vis spectroscopy. The crystal structure of the NPs was found to be hexagonal wurtzite with a particle size of 30.39 nm, a surface area of 13.826 m²/g, and a pore volume of 0.0475 cm³/g. The zeta potential of the NPs was −22.1 mV, and they showed a mass loss of 33% at about 750 °C, indicating their durability at high temperatures. Kinetic and isotherm models were used to determine the most suitable model for PCM removal, with the Elovich model showing an R² value of 0.989 and the Redlich-Peterson model showing an R² value of 0.999. The adsorption efficiency of PCM was 23 mg/g, demonstrating the potential of OB-ZnO NPs for removing pharmaceutical wastes.
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