An Updated Comprehensive Kinetic Model of Hydrogen Combustion

An Updated Comprehensive Kinetic Model of Hydrogen Combustion

(Vol. 36, p. 566-575 (2004)) | Juan Li, Zhenwei Zhao, Andrei Kazakov, and Frederick L. Dryer
The paper presents an updated comprehensive kinetic model for hydrogen combustion, based on the work of Mueller et al. [1] and recent advancements in kinetic and thermodynamic data. The revised mechanism is validated against a wide range of experimental conditions, including shock tubes, flow reactors, and laminar premixed flames. The model demonstrates excellent agreement with experimental observations, particularly in high-pressure laminar flame speed and shock tube ignition results. Key reactions, such as H+OH+M, are found to be significant only at high pressures for laminar flame speed propagation. The updated mechanism includes revised thermodynamic data and rate coefficients for reactions (R1) and (R2), which are crucial for the system's behavior. The sensitivity analysis highlights the importance of these reactions and their rate constants. The mechanism is also compared with various experimental data, showing good agreement in laminar flame speed, shock tube ignition delay, and species profiles in flow reactors and burner-stabilized flames. The updated model is available in electronic form compatible with CHEMKIN II.The paper presents an updated comprehensive kinetic model for hydrogen combustion, based on the work of Mueller et al. [1] and recent advancements in kinetic and thermodynamic data. The revised mechanism is validated against a wide range of experimental conditions, including shock tubes, flow reactors, and laminar premixed flames. The model demonstrates excellent agreement with experimental observations, particularly in high-pressure laminar flame speed and shock tube ignition results. Key reactions, such as H+OH+M, are found to be significant only at high pressures for laminar flame speed propagation. The updated mechanism includes revised thermodynamic data and rate coefficients for reactions (R1) and (R2), which are crucial for the system's behavior. The sensitivity analysis highlights the importance of these reactions and their rate constants. The mechanism is also compared with various experimental data, showing good agreement in laminar flame speed, shock tube ignition delay, and species profiles in flow reactors and burner-stabilized flames. The updated model is available in electronic form compatible with CHEMKIN II.
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