Attosecond Delays in X-ray Molecular Ionization

Attosecond Delays in X-ray Molecular Ionization

20 Feb 2024 | Taran Driver, Miles Mountney, Jun Wang, Lisa Ortmann, Andre Al-Haddad, Nora Berrah, Christoph Bostedt, Elio G. Champefois, Louis F. DiMauro, Joseph Duris, Douglas Garratt, James M. Glownia, Zhaoheng Guo, Daniel Haxton, Erik Isele, Igor Ivanov, Jiabao Ji, Andrei Kamalov, Siqi Li, Ming-Fu Lin, Jon P. Marangos, Razib Obaid, Jordan T. O'Neal, Philipp Rosenberger, Niranjan H. Shivaram, Anna L. Wang, Peter Walter, Thomas J. A. Wolf, Hans Jakob Wörner, Zhen Zhang, Philip H. Bucksbaum, Matthias F. Kling, Alexandra S. Landsman, Robert R. Lucchese, Agapi Emmanouilidou, Agostino Marinelli, James P. Cryan
The study investigates attosecond delays in x-ray molecular ionization, specifically focusing on core-level electron photoemission from nitric oxide (NO). Using attosecond x-ray pulses from a free-electron laser (XFEL), the researchers measured the time delay between electrons emitted from the oxygen and nitrogen $K$-shells. The measurements revealed unexpectedly large delays, up to 700 attoseconds, near the oxygen $K$-shell threshold. These delays are attributed to various factors, including transient trapping of the photoelectron due to shape resonances, collisions with the Auger-Meitner electron, and multi-electron scattering effects. The results demonstrate how x-ray attosecond experiments, combined with theoretical modeling, can provide insights into the complex correlated dynamics of core-level photoionization. The study also highlights the importance of electron correlation effects in accurately modeling the photoionization process.The study investigates attosecond delays in x-ray molecular ionization, specifically focusing on core-level electron photoemission from nitric oxide (NO). Using attosecond x-ray pulses from a free-electron laser (XFEL), the researchers measured the time delay between electrons emitted from the oxygen and nitrogen $K$-shells. The measurements revealed unexpectedly large delays, up to 700 attoseconds, near the oxygen $K$-shell threshold. These delays are attributed to various factors, including transient trapping of the photoelectron due to shape resonances, collisions with the Auger-Meitner electron, and multi-electron scattering effects. The results demonstrate how x-ray attosecond experiments, combined with theoretical modeling, can provide insights into the complex correlated dynamics of core-level photoionization. The study also highlights the importance of electron correlation effects in accurately modeling the photoionization process.
Reach us at info@study.space
[slides and audio] Attosecond delays in X-ray molecular ionization.