Bright and stable near-infrared lead-free perovskite light-emitting diodes

Bright and stable near-infrared lead-free perovskite light-emitting diodes

February 2024 | Fanglong Yuan, Giulia Folpini, Tianjun Liu, Utkarsh Singh, Antonella Treglia, Jia Wei Melvin Lim, Johan Klarbring, Sergei I. Simak, Igor A. Abrikosov, Tze Chien Sum, Annamaria Petrozza, Feng Gao
This article presents the development of near-infrared (NIR) light-emitting diodes (LEDs) with wavelengths beyond 900 nm using all-inorganic tin perovskite CsSnI₃. The study addresses the challenges of low radiance and poor operational stability in state-of-the-art long-wavelength NIR LEDs. By controlling the crystallization process of CsSnI₃ precursors in tin-rich conditions, the researchers achieved improved performance through rational manipulation of p-doping. The resulting LEDs emit at 948 nm with a high radiance of 226 W sr⁻¹ m⁻² and a long operational half-lifetime of 39.5 h at a high current density of 100 mA cm⁻². The study demonstrates that intrinsic p-doping in tin-based perovskites can be beneficial for achieving high-performance NIR LEDs when controlled. The incorporation of NPTU and SnF₂ reduced carrier trap density and improved radiative efficiency. The LEDs also showed excellent stability, with a half-lifetime significantly longer than that of other soft-material-based NIR LEDs. The study highlights the potential of tin-based perovskites for high-performance NIR LEDs and opens new opportunities for electrically pumped lasers. The research provides insights into the electronic structure and recombination dynamics of tin-based perovskites, showing that they have a much lower Auger recombination rate than lead-based perovskites, which is beneficial for light emission. The findings suggest that tin-based perovskites could be a promising alternative for high-performance NIR LEDs.This article presents the development of near-infrared (NIR) light-emitting diodes (LEDs) with wavelengths beyond 900 nm using all-inorganic tin perovskite CsSnI₃. The study addresses the challenges of low radiance and poor operational stability in state-of-the-art long-wavelength NIR LEDs. By controlling the crystallization process of CsSnI₃ precursors in tin-rich conditions, the researchers achieved improved performance through rational manipulation of p-doping. The resulting LEDs emit at 948 nm with a high radiance of 226 W sr⁻¹ m⁻² and a long operational half-lifetime of 39.5 h at a high current density of 100 mA cm⁻². The study demonstrates that intrinsic p-doping in tin-based perovskites can be beneficial for achieving high-performance NIR LEDs when controlled. The incorporation of NPTU and SnF₂ reduced carrier trap density and improved radiative efficiency. The LEDs also showed excellent stability, with a half-lifetime significantly longer than that of other soft-material-based NIR LEDs. The study highlights the potential of tin-based perovskites for high-performance NIR LEDs and opens new opportunities for electrically pumped lasers. The research provides insights into the electronic structure and recombination dynamics of tin-based perovskites, showing that they have a much lower Auger recombination rate than lead-based perovskites, which is beneficial for light emission. The findings suggest that tin-based perovskites could be a promising alternative for high-performance NIR LEDs.
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