29 January 2024 | Mouhamad S. Diallo, Tan Shi, Yaqian Zhang, Xinxing Peng, Imtiaz Shozib, Yan Wang, Lincoln J. Miara, Mary C. Scott, Qingsong Howard Tu, Gerbrand Ceder
This study investigates the effect of solid-electrolyte pellet density on the failure mechanisms of solid-state batteries (SSBs). The research highlights that Li-filament growth is suppressed in pellets with a relative density exceeding ~95%. Below this threshold, battery short circuits occur more frequently due to faster Li-filament growth in the percolating pores of the pellet. The microstructural properties of 75%Li2S – 25%PSx (LPS) pellets at various relative densities are quantified using focused ion beam-scanning electron microscopy tomography and permeability tests. Modeling results provide insights into Li-filament growth within pores ranging from 0.2 to 2 μm. The findings improve understanding of SSB failure modes and provide guidelines for designing dendrite-free SSBs. The study emphasizes the importance of optimizing pellet density to prevent Li-filament growth and enhance battery safety and performance.This study investigates the effect of solid-electrolyte pellet density on the failure mechanisms of solid-state batteries (SSBs). The research highlights that Li-filament growth is suppressed in pellets with a relative density exceeding ~95%. Below this threshold, battery short circuits occur more frequently due to faster Li-filament growth in the percolating pores of the pellet. The microstructural properties of 75%Li2S – 25%PSx (LPS) pellets at various relative densities are quantified using focused ion beam-scanning electron microscopy tomography and permeability tests. Modeling results provide insights into Li-filament growth within pores ranging from 0.2 to 2 μm. The findings improve understanding of SSB failure modes and provide guidelines for designing dendrite-free SSBs. The study emphasizes the importance of optimizing pellet density to prevent Li-filament growth and enhance battery safety and performance.