This study explores the production of ethylene (C₂H₄) from carbonate solutions using a bipolar membrane (BPM) electrolysis system. The research focuses on the use of Cu–Ag catalysts to enhance the Faradaic efficiency (FE) of CO₂ reduction to ethylene. The system involves a membrane electrode assembly (MEA) with a BPM, which allows for the direct release of CO₂ stored in carbonate solutions through a pH swing process driven by water dissociation within the BPM. The study demonstrates that the BPM-MEA system can achieve a 10% FE for CO₂ to ethylene conversion, with a partial current density of 10 mA/cm². The system maintains approximately 0% CO₂ concentration in the outlet over 24 hours, indicating high efficiency in CO₂ utilization. Operating at elevated temperatures, such as 50°C, improves the FE and current densities for ethylene production. The study also evaluates the feasibility of the system for CO₂ generation and conversion, estimating potential energy and process efficiencies. The BPM-MEA system offers innovative solutions for carbon capture and conversion, but further research and optimization are needed to fully harness its potential for a sustainable future. The study highlights the importance of optimizing catalysts, operating conditions, and system design to enhance the efficiency and sustainability of CO₂ conversion processes. The results suggest that the BPM-MEA system is a promising approach for efficient CO₂ generation and conversion, effectively linking carbon capture technologies to the sustainable production of chemicals.This study explores the production of ethylene (C₂H₄) from carbonate solutions using a bipolar membrane (BPM) electrolysis system. The research focuses on the use of Cu–Ag catalysts to enhance the Faradaic efficiency (FE) of CO₂ reduction to ethylene. The system involves a membrane electrode assembly (MEA) with a BPM, which allows for the direct release of CO₂ stored in carbonate solutions through a pH swing process driven by water dissociation within the BPM. The study demonstrates that the BPM-MEA system can achieve a 10% FE for CO₂ to ethylene conversion, with a partial current density of 10 mA/cm². The system maintains approximately 0% CO₂ concentration in the outlet over 24 hours, indicating high efficiency in CO₂ utilization. Operating at elevated temperatures, such as 50°C, improves the FE and current densities for ethylene production. The study also evaluates the feasibility of the system for CO₂ generation and conversion, estimating potential energy and process efficiencies. The BPM-MEA system offers innovative solutions for carbon capture and conversion, but further research and optimization are needed to fully harness its potential for a sustainable future. The study highlights the importance of optimizing catalysts, operating conditions, and system design to enhance the efficiency and sustainability of CO₂ conversion processes. The results suggest that the BPM-MEA system is a promising approach for efficient CO₂ generation and conversion, effectively linking carbon capture technologies to the sustainable production of chemicals.