August 10, 2017 | He Huang, Maryna I. Bodnarchuk, Stephen V. Kershaw, Maksym V. Kovalenko, and Andrey L. Rogach
This perspective article provides an overview of the basic structural and optical properties of lead halide perovskite (LHP) colloidal nanocrystals (NCs), highlighting their differences and similarities with conventional II-VI and III-V semiconductor quantum dots. It emphasizes two key issues: the advantages of defect tolerance and the need to improve stability under environmental conditions. The article discusses the blue-shifted emission from CsPbBr3 NCs and explores synthetic strategies for fabricating stable LHP NC materials with emission in the red and infrared parts of the optical spectrum, focusing on mixed-cation compounds guided by the Goldschmidt tolerance factor. The defect tolerance of LHP NCs offers inspiration for searching for similar attributes in other heavy metal-free compounds. The article concludes with a discussion on the potential applications of colloidal LHP NCs in backlighting for liquid-crystal displays.This perspective article provides an overview of the basic structural and optical properties of lead halide perovskite (LHP) colloidal nanocrystals (NCs), highlighting their differences and similarities with conventional II-VI and III-V semiconductor quantum dots. It emphasizes two key issues: the advantages of defect tolerance and the need to improve stability under environmental conditions. The article discusses the blue-shifted emission from CsPbBr3 NCs and explores synthetic strategies for fabricating stable LHP NC materials with emission in the red and infrared parts of the optical spectrum, focusing on mixed-cation compounds guided by the Goldschmidt tolerance factor. The defect tolerance of LHP NCs offers inspiration for searching for similar attributes in other heavy metal-free compounds. The article concludes with a discussion on the potential applications of colloidal LHP NCs in backlighting for liquid-crystal displays.