Real Time and Highly Sensitive Sub-Wavelength 2D Hybrid Perovskite Photodetectors

Real Time and Highly Sensitive Sub-Wavelength 2D Hybrid Perovskite Photodetectors

2024 | Rosanna Mastroia, Karl Jonas Riisnaes, Agnes Bacon, Ioannis Leontis, Hoi Tung Lam, Mohammed Ali Saleh Alshehri, David Colridge, Tsz Hin Edmund Chan, Adolfo De Sanctis, Luisa De Marco, Laura Polimeno, Annalisa Coriolano, Anna Moliterni, Vincent Olieric, Cinzia Giannini, Steven Hepplestone, Monica Felicia Craciun, and Saverio Russo
This study presents the development of nano-scale 2D-fluorinated phenethylammonium lead iodide (F-PEAI) planar photodetectors fabricated entirely in atmosphere using standard electron beam lithography. These photodetectors exhibit exceptional performance, including a record room temperature detectivity of >5×10¹⁷ Jones, a fast photoresponse (rise time 1.5 ns), an extraordinarily large linear dynamic range (228 dB), and a photo-responsivity of ≈1100 AW⁻¹. The devices are stable from room temperature down to 4 K and can be reliably fabricated on a wide range of substrates, including flexible wearable media, without the need for planarization or atomically thin dielectrics. The photodetectors are also suitable for high-definition imaging due to their sub-wavelength pixel size of 100 nm. The 2D F-PEAI photodetectors demonstrate outstanding performance, rivaling commercial silicon photodiodes, and are compatible with a wide range of substrates. The study also shows that these photodetectors can be used for imaging technologies, with a 2D F-PEAI photodetector used to image a University of Exeter logo. The devices are also highly sensitive and stable, with a linear scaling of photocurrent with irradiance over 11 decades, corresponding to 228 dB. The study highlights the potential of 2D F-PEAI photodetectors for applications in extremely low-light conditions and high-definition imaging. The results demonstrate the potential of 2D F-PEAI photodetectors for use in optoelectronic applications, with performance comparable or superior to research-grade commercial Si or InGaAs photodetectors. The study also shows that these photodetectors are stable to thermal cycling over a wide temperature range from room temperature down to 4 K. The devices are fabricated on flexible substrates and retain their performance even after 1000 bending cycles in atmosphere conditions. The study also demonstrates the use of 2D F-PEAI photodetectors for high-definition imaging, with a 100 nm pixel size capable of imaging a laser beam profile with a spatial resolution of 100 nm. The results highlight the potential of 2D F-PEAI photodetectors for use in optoelectronic applications, with performance comparable or superior to research-grade commercial Si or InGaAs photodetectors.This study presents the development of nano-scale 2D-fluorinated phenethylammonium lead iodide (F-PEAI) planar photodetectors fabricated entirely in atmosphere using standard electron beam lithography. These photodetectors exhibit exceptional performance, including a record room temperature detectivity of >5×10¹⁷ Jones, a fast photoresponse (rise time 1.5 ns), an extraordinarily large linear dynamic range (228 dB), and a photo-responsivity of ≈1100 AW⁻¹. The devices are stable from room temperature down to 4 K and can be reliably fabricated on a wide range of substrates, including flexible wearable media, without the need for planarization or atomically thin dielectrics. The photodetectors are also suitable for high-definition imaging due to their sub-wavelength pixel size of 100 nm. The 2D F-PEAI photodetectors demonstrate outstanding performance, rivaling commercial silicon photodiodes, and are compatible with a wide range of substrates. The study also shows that these photodetectors can be used for imaging technologies, with a 2D F-PEAI photodetector used to image a University of Exeter logo. The devices are also highly sensitive and stable, with a linear scaling of photocurrent with irradiance over 11 decades, corresponding to 228 dB. The study highlights the potential of 2D F-PEAI photodetectors for applications in extremely low-light conditions and high-definition imaging. The results demonstrate the potential of 2D F-PEAI photodetectors for use in optoelectronic applications, with performance comparable or superior to research-grade commercial Si or InGaAs photodetectors. The study also shows that these photodetectors are stable to thermal cycling over a wide temperature range from room temperature down to 4 K. The devices are fabricated on flexible substrates and retain their performance even after 1000 bending cycles in atmosphere conditions. The study also demonstrates the use of 2D F-PEAI photodetectors for high-definition imaging, with a 100 nm pixel size capable of imaging a laser beam profile with a spatial resolution of 100 nm. The results highlight the potential of 2D F-PEAI photodetectors for use in optoelectronic applications, with performance comparable or superior to research-grade commercial Si or InGaAs photodetectors.
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