The fourth edition of "Tables of Physical and Chemical Constants" by G. W. C. Kaye and T. H. Laby, published in 1921, is a valuable resource for physicists and scientists. The authors' careful selection of data from a vast amount of material makes this edition more useful than other larger collections. This edition includes updates on X-ray wavelengths and sparking voltages, as well as expanded tables on heat and gravity constants. All atomic weight data has been recalculated based on the latest values from the International Atomic Weight Committee, ensuring accuracy. The book also covers the physical constants of commonly used materials comprehensively. However, it highlights the lack of experimental data for some useful constants, which should be addressed in future research.The fourth edition of "Tables of Physical and Chemical Constants" by G. W. C. Kaye and T. H. Laby, published in 1921, is a valuable resource for physicists and scientists. The authors' careful selection of data from a vast amount of material makes this edition more useful than other larger collections. This edition includes updates on X-ray wavelengths and sparking voltages, as well as expanded tables on heat and gravity constants. All atomic weight data has been recalculated based on the latest values from the International Atomic Weight Committee, ensuring accuracy. The book also covers the physical constants of commonly used materials comprehensively. However, it highlights the lack of experimental data for some useful constants, which should be addressed in future research.