The physics of simple metal clusters: self-consistent jellium model and semiclassical approaches

The physics of simple metal clusters: self-consistent jellium model and semiclassical approaches

July 1993 | Matthias Brack
The jellium model is a simplified theoretical framework used to describe the electronic structure of simple metal clusters. It treats the ionic cores as a uniform positive background and focuses on the delocalized valence electrons. This model has been successful in explaining the electronic shell structure and other properties of alkali and simple metal clusters. The model is based on the self-consistent calculation of the electronic density and includes various approximations such as the local-density approximation (LDA) for exchange and correlation effects, and semiclassical approximations for the single-particle density matrix. These approaches allow for the connection of cluster properties to bulk and macroscopic properties. The physical properties discussed include ground-state binding energies, ionization potentials, and dipole polarizabilities. The model has been extended to include deformations and finite-temperature effects, and has been used to study the supershell structure in large alkali clusters. The jellium model is also compared with other theoretical approaches such as quantum chemistry and molecular dynamics. The model's success in describing the electronic structure of clusters is attributed to its simplicity and ability to capture the essential physics of the system. However, it neglects the ionic structure, which limits its applicability to certain types of metals. The model has been used to study the behavior of large clusters and their connection to the bulk, and has been shown to provide accurate results for certain properties of metal clusters. The jellium model is a valuable tool for understanding the electronic structure of metal clusters and has been widely used in theoretical studies of these systems.The jellium model is a simplified theoretical framework used to describe the electronic structure of simple metal clusters. It treats the ionic cores as a uniform positive background and focuses on the delocalized valence electrons. This model has been successful in explaining the electronic shell structure and other properties of alkali and simple metal clusters. The model is based on the self-consistent calculation of the electronic density and includes various approximations such as the local-density approximation (LDA) for exchange and correlation effects, and semiclassical approximations for the single-particle density matrix. These approaches allow for the connection of cluster properties to bulk and macroscopic properties. The physical properties discussed include ground-state binding energies, ionization potentials, and dipole polarizabilities. The model has been extended to include deformations and finite-temperature effects, and has been used to study the supershell structure in large alkali clusters. The jellium model is also compared with other theoretical approaches such as quantum chemistry and molecular dynamics. The model's success in describing the electronic structure of clusters is attributed to its simplicity and ability to capture the essential physics of the system. However, it neglects the ionic structure, which limits its applicability to certain types of metals. The model has been used to study the behavior of large clusters and their connection to the bulk, and has been shown to provide accurate results for certain properties of metal clusters. The jellium model is a valuable tool for understanding the electronic structure of metal clusters and has been widely used in theoretical studies of these systems.
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